322 Search Results

Addition of Ph₂SiH₂ to [(depe)₂Mo(N)][BAr^F₄] (depe = 1,2-bis(diethylphosphino)ethane, BAr^F₄ = B(3,5-(CF₃)₂C₆H₃)₄) at 60 °C generated the silyl imido molybdenum hydride complex, trans- [(depe)₂Mo(NSiHPh₂)H][BAr^F₄], a surrogate for a proposed intermediate complex in the photodriven hydrogenation to free ammonia. Irradiation of a THF solution of trans-[(depe)₂Mo(NSiHPh₂)H]- [BAr^F₄] with blue light under H₂ produced free amine along with [(depe)₂MoH₅][BAr^F₄] in 76% yield. This transformation occurred in the absence of a precious metal photocatalyst, suggesting that it was needed only for the initial addition of H₂ to the molybdenum nitride during the first N−H bond-forming step in the photodriven hydrogenation. Deuterium labeling and crossovermore » studies support concerted Si−H bond addition across the Mo≡N bond, enabled by the nucleophilicity of the nitride. Subsequent hydrogenation involves an intramolecular H migration from Mo to the imido ligand, as supported by electronic absorption spectroscopy, transient absorption spectroscopy, initial rate measurements, and deuterium kinetic isotope effect measurements. These findings provide insights into the photodriven hydrogenation of [(depe)₂Mo(N)][BAr^F₄] to ammonia and the role of the photocatalyst in this transformation.« less

Reduction of (depe)₂CrCl₂ (depe = 1,2-bis- (diethylphosphino)ethane) and (dep-benz)₂CrCl₂ (dep-benz = 1,2-bis(diethylphosphino)benzene) under 1 atm of N₂ furnished the dinitrogen complexes (depe)₂Cr(N₂)₂ and (dep-benz)₂Cr(N₂)₂, respectively. One-electron oxidation of these products with FcBAr^F ₄ (Fc = ferrocenium, BAr^F ₄ = B(3,5-(CF₃)₂C₆H₃)₄) yielded the unusual, high-spin tetrahedral complexes [(depe)₂Cr][BAr^F ₄] and [(dep-benz)₂Cr][BAr^F ₄] with concomitant loss of dinitrogen. Reaction of the chromium(I) derivatives with Ph₃CN₃ furnished rare examples of chromium(IV) nitrides as confirmed spectroscopically and by X-ray crystallography. While [(depe)₂Cr(≡N)][BAr^F ₄] underwent association of isocyanides accompanied by partial ligand dissociation, neither chromium nitride was reactive toward H₂ or diphenylsilane under thermal ormore » photochemical conditions. These results distinguish the unique properties of the chromium(IV) nitrides as compared to heavier group 6 congeners and demonstrate both the feasibility of nitride synthesis and the limitations of dinitrogen cleavage and subsequent N−H bond formation.« less

A search is performed for dark matter produced in association with bottom quarks and a pair of electrons or muons in data collected with the CMS detector at the LHC, corresponding to 138 fb$$^{−1}$$ of integrated luminosity of proton-proton collisions at a center-of-mass energy of 13 TeV. For the first time at the LHC, the associated production of a bottom quark-antiquark pair and a new heavy neutral Higgs boson (H) that subsequently decays into a leptonically decaying Z boson and a pseudoscalar (a) is explored. The latter acts as a dark matter mediator in the context of the two Higgsmore » doublet model plus a pseudoscalar (2HDM+a). Multivariate techniques that target a wide range of mass configurations for the H and a particles are used. The observations are consistent with the expectations from standard model processes. Upper limits at 95% confidence level are set on the product of cross section and branching fraction of the new particles, ranging from 10$$^{−2}$$ pb for an H mass of 400 GeV to 10$$^{−3}$$ pb for an H mass of 2000 GeV. Constraints on the parameter space of a benchmark 2HDM+a model are derived and compared with expectations in the context of cosmological predictions.[graphic not available: see fulltext]« less

A search for the pair production of heavy spin- $1/2$ or spin- $3/2$ resonances ( $t^{*}$ ) in proton-proton collisions at $\sqrt{s}=13\mathrm{TeV}$ is presented. Data collected with the CMS detector at the CERN LHC from 2016 to 2018 corresponding to an integrated luminosity of $138{\mathrm{fb}}^{-1}$ are used. The analysis targets benchmark signal scenarios where one $t^{*}$ decays into a top quark ( $t$ ) and a photon ( $\gamma$ ), and the other into a $t$ quarkmore » and a gluon ( $g$ ), i.e., $pp\to t^{*}\overline{t^{*}}\to tt\gamma g$ . All-hadronic final states from the $t$ pair decay chain are selected using jet substructure techniques. The signal is probed as a function of the $t^{*}$ candidate mass, which is reconstructed using the photon and a top quark candidate jet. No significant deviation from the background-only hypothesis is found. Observed (expected) upper limits on the signal cross section at 95% confidence level are set, excluding masses of spin- $1/2$ $t^{*}$ particles below 930 (930) GeV and spin- $3/2$ $t^{*}$ particles below 1330 (1390) GeV. This analysis marks the first search for heavy resonances in the $t\overline{t}\gamma g$ channel. Exploiting the high-energy photon to reduce the backgrounds, this search achieves sensitivity competitive with $pp\to t^{*}\overline{t^{*}}\to t\overline{t}gg$ searches for spin- $1/2$ $t^{*}$ despite the small expected $t^{*}\to t\gamma$ branching fraction.« less

The ratio between the B$$_\mathrm{c}^+$$$$\to$$ J/$$ψ$$$τ^+ν_τ$$ and B$$_\mathrm{c}^+$$$$\to$$ J/$$ψ$$$μ^+ν_μ$$ branching fractions is measured using a data sample of proton-proton collisions collected by CMS at a center-of-mass energy of 13 TeV in the years 2016$$-$$2018 and corresponding to an integrated luminosity of 138 fb$$^{-1}$$. The J$/ψ$ meson is identified through its J$/ψ$$$$\to$$$$μ^+μ^-$ decay and the tau lepton is reconstructed in the hadronic three-prong final state. The measured ratio of branching fractions in this tau decay mode, $$\mathcal{R}^\text{had}_{\mathrm{J}/ψ}$$ = 1.04 $$_{-0.44}^{+0.50}$$, is combined with the previous analysis based on the $τ^+$$$$\to$$$$μ^+ν_μ\barν_τ$$ leptonic decay channel, leading to $$\mathcal{R}_{\mathrm{J}/ψ}$$ = 0.49 $$\pm$$ 0.26. Asmore » this result is consistent with the standard model prediction of 0.258 $$\pm$$ 0.004, no evidence of lepton flavor universality violation is found.« less

A novel anomaly detection algorithm is presented. The Wasserstein normalized autoencoder (WNAE) is a normalized probabilistic model that minimizes the Wasserstein distance between the learned probability distribution—a Boltzmann distribution where the energy is the reconstruction error of the autoencoder (AE)—and the distribution of the training data. This algorithm has been developed and applied to the identification of semivisible jets—conical sprays of visible standard model (SM) particles and invisible dark matter states—with the CMS experiment at the CERN LHC. Trained on jets of particles from simulated SM processes, the WNAE is shown to learn the probability distribution of the input datamore » in a fully unsupervised fashion, such that it effectively identifies new physics jets as anomalies. The model exhibits stable, convergent training and recovers strong classification performance for a wide range of signals against the selected background process, for which a standard AE fails because of outlier reconstruction. In addition, the model improves upon standard normalized autoencoders while remaining fully agnostic to the signal. The WNAE directly tackles the problem of outlier reconstruction, a common failure mode of autoencoders in anomaly detection tasks.« less

The Higgs boson (H) decay width is determined from the ratio of off- and on-shell production of H $$\to$$ WW $$\to$$ e$νμν$ using proton-proton collision data corresponding to an integrated luminosity of 138 fb$$^{-1}$$ collected at $$\sqrt{s}$$ = 13 TeV by the CMS experiment at the Large Hadron Collider. The off-shell signal strength is measured as $$μ_\text{off-shell}$$ = 1.2 $$^{+0.8}_{-0.7}$$. The Higgs boson total decay width is $$Γ_\text{H}$$ = 3.9 $$^{+2.7}_{-2.2}$$ MeV, in agreement with the standard model prediction. The uncertainty in this result represents a factor of three improvement over the previous CMS result in this decay channel.

Differential top quark pair production cross sections are measured in the dilepton final states e$$^{+}$$e$$^{−}$$, μ$$^{+}$$μ$$^{−}$$, and e$$^{±}$$μ$$^{∓}$$, as a function of kinematic variables of the two-neutrino system: the transverse momentum $$ {p}_{\textrm{T}}^{\nu \nu} $$ of the dineutrino system, the minimum distance in azimuthal angle between $$ {\overrightarrow{p}}_{\textrm{T}}^{\nu \nu} $$ and leptons, and in two dimensions in bins of both observables. The measurements are performed using CERN LHC proton-proton collisions at $$ \sqrt{s}=13 $$ TeV, recorded by the CMS detector between 2016 and 2018, corresponding to an integrated luminosity of 138 fb$$^{−1}$$. The measured cross sections are unfolded to themore » particle level using an unregularized least squares method. Results are compared with predictions by the standard model of particle physics, and found to be in agreement with theoretical calculations as well as Monte Carlo simulations.[graphic not available: see fulltext]« less

The results of a search for the production of two scalar bosons in final states with two photons and two tau leptons are presented. The search considers both nonresonant production of a Higgs boson pair, HH, and resonant production via a new boson X which decays either to HH or to H and a new scalar Y. The analysis uses up to 138 fb$$^{−1}$$ of proton-proton collision data, recorded between 2016 and 2018 by the CMS experiment at the LHC at a center-of-mass energy of 13 TeV. No evidence for signal is found in the data. For the nonresonant production,more » the observed (expected) upper limit at 95% confidence level (CL) on the HH production cross section is set at 930 (740) fb, corresponding to 33 (26) times the standard model prediction. At 95% CL, HH production is observed (expected) to be excluded for values of κ$$_{λ}$$ outside the range between −12 (−9.4) and 17 (15). Observed (expected) upper limits at 95% CL for the X → HH cross section are found to be within 160 to 2200 (200 to 1800) fb, depending on the mass of X. In the X → Y(ττ)H(γγ) search, the observed (expected) upper limits on the product of the production cross section and decay branching fractions vary between 0.059–1.2 fb (0.087–0.68 fb). For the X → Y(γγ)H(ττ) search the observed (expected) upper limits on the product of the production cross section and Y → γγ branching fraction vary between 0.69–15 fb (0.73–8.3 fb) in the low Y mass search, tightening constraints on the next-to-minimal supersymmetric standard model, and between 0.64–10 fb (0.70–7.6 fb) in the high Y mass search.[graphic not available: see fulltext]« less

A measurement of the angular structure of inclusive jets and those containing a prompt D$$^{0}$$ meson in proton-proton collisions at the LHC at a center-of-mass energy of 5.02 TeV is presented. The data corresponding to an integrated luminosity of 301 pb$$^{−1}$$ were collected by the CMS experiment in 2017. Two jet grooming algorithms, late-k$$_{T}$$ and soft drop, are used to study the intrajet radiation pattern using iterative Cambridge-Aachen declustering. The splitting-angle distributions of jets with transverse momentum (p$$_{T}$$) of around 100 GeV, obtained with these two algorithms, show that there is a shift of the distribution for jets containing amore » prompt D$$^{0}$$ meson with respect to inclusive jets. The suppression of emissions at small angles observed in the late-k$$_{T}$$ grooming approach is consistent with the dead-cone effect, whereas the similar suppression for splittings selected with the soft-drop algorithm appears to be induced by gluon splitting to charm quark-antiquark pairs at large angles. The measured distributions are corrected to the particle level and can be used to constrain model predictions for the substructure of high-p$$_{T}$$ charm quark jets.[graphic not available: see fulltext]« less